dorsal/arxiv
View SchemaActive alignment-driven coarsening in confined near-critical fluids
| Authors | Parameshwaran A, Bhaskar Sen Gupta |
|---|---|
| Categories | |
| ArXiv ID | 2601.09181vv1 |
| URL | https://arxiv.org/abs/2601.09181 |
| License | http://creativecommons.org/licenses/by/4.0/ |
Abstract
We investigate vapor-liquid phase separation of an active near critical Lennard-Jones fluid confined within a cylindrical pore using molecular dynamics simulations. Activity is introduced via Vicsek-type alignment interactions, enabling a systematic study of how self-propulsion modifies domain morphology and coarsening kinetics under quasi-one-dimensional confinement. In the passive limit, the system undergoes early-time spinodal decomposition (diffusive growth characterized by the Lifshitz-Slyozov exponent $\alpha = 1/3$), followed by the formation of periodically modulated, plug-like liquid domains along the pore axis. At late times, coarsening becomes kinetically arrested, and the system remains trapped in a metastable striped state. Introducing activity destabilizes this arrested morphology by enhancing collective domain transport, leading to frequent domain mergers and complete phase separation at sufficiently high activity. The late-stage coarsening then exhibits a crossover to faster, ballistic growth with an effective exponent $\alpha = 2/3$, consistent with a cluster-coalescence mechanism. Analysis of two-point correlation functions and structure factors confirms dynamic scaling across all activity regimes. Our results demonstrate that alignment-induced activity can overcome confinement-driven kinetic arrest, providing new insight into phase separation in confined active fluids. The relevant growth laws are analyzed and interpreted using appropriate theoretical frameworks.
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"abstract": "We investigate vapor-liquid phase separation of an active near critical Lennard-Jones fluid confined within a cylindrical pore using molecular dynamics simulations. Activity is introduced via Vicsek-type alignment interactions, enabling a systematic study of how self-propulsion modifies domain morphology and coarsening kinetics under quasi-one-dimensional confinement. In the passive limit, the system undergoes early-time spinodal decomposition (diffusive growth characterized by the Lifshitz-Slyozov exponent $\\alpha = 1/3$), followed by the formation of periodically modulated, plug-like liquid domains along the pore axis. At late times, coarsening becomes kinetically arrested, and the system remains trapped in a metastable striped state. Introducing activity destabilizes this arrested morphology by enhancing collective domain transport, leading to frequent domain mergers and complete phase separation at sufficiently high activity. The late-stage coarsening then exhibits a crossover to faster, ballistic growth with an effective exponent $\\alpha = 2/3$, consistent with a cluster-coalescence mechanism. Analysis of two-point correlation functions and structure factors confirms dynamic scaling across all activity regimes. Our results demonstrate that alignment-induced activity can overcome confinement-driven kinetic arrest, providing new insight into phase separation in confined active fluids. The relevant growth laws are analyzed and interpreted using appropriate theoretical frameworks.",
"arxiv_id": "2601.09181",
"authors": [
"Parameshwaran A",
"Bhaskar Sen Gupta"
],
"categories": [
"cond-mat.soft",
"cond-mat.mtrl-sci",
"cond-mat.stat-mech",
"physics.bio-ph"
],
"license": "http://creativecommons.org/licenses/by/4.0/",
"title": "Active alignment-driven coarsening in confined near-critical fluids",
"url": "https://arxiv.org/abs/2601.09181",
"version": "v1"
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